(Thiocyanato-κN)bis(thiosemicarbazide-κS)copper(I)
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چکیده
In the title complex, [Cu(CH(5)N(3)S)(2)(NCS)], the non-H part of the mol-ecule is strictly planar, lying on the mirror plane at y = 0.25. The Cu atom lies at the centre of a triangle formed by the coordination of three monodentate groups, viz. two thio-semicarbazide ligands and one NCS(-) anion. Weak inter-molecular N-H⋯S inter-actions generate a two-dimensional network.
منابع مشابه
Di-μ-thiosemicarbazide-κ4 S:S-bis[bis(thiosemicarbazide-κS)copper(I)] diiodide
The title compound, [Cu(2){SC(NH(2))NHNH(2)}(6)]I(2), was obtained by the reaction of CuI and thio-semicarbazide (TSCZ) in acetonitrile. Each Cu(I) ion is coordinated by four S atoms of the TSCZ ligands, forming a tetra-hedral geometry. Centrosymmetric dimers are formed by two coordination tetra-hedra sharing a common edge, with a Cu⋯Cu distance of 2.8236 (14) Å. The I(-) ion does not have any ...
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The N-heterocyclic ligand in the title compound, [Cu(NCS)(C(15)H(13)N(5)S(2))](n), coordinates to the Cu(I) atom through its pyridine N-donor site, and adjacent metal atoms are bridged by the thio-cyanate ion, forming a helical chain along the b axis. The geometry of the metal atom is tetra-hedral owing to a somewhat long intra-molecular Cu-S inter-action of 2.5621 (9) Å.
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